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Cover Picture: Oxidative Fragmentation of the Bridged β-Triketone Core of Hyperforin (Eur. J. Org. Chem. 6/2004)

✍ Scribed by Luisella Verotta; Erminio Lovaglio; Olov Sterner; Giovanni Appendino; Ezio Bombardelli

Publisher: John Wiley and Sons
Year: 2004
Tongue: English
Weight: 283 KB
Volume: 2004
Category: Article
ISSN: 1434-193X
DOI: 10.1002/ejoc.200490012

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## Abstract The β‐triketone core of the antidepressant phloroglucinol hyperforin (**1**) undergoes a series of peroxide‐induced oxidative rearrangements leading to compound **5**, which is formed by opening of ring A, and compound **6**, which is formed by removal of the C‐1 carbonyl bridge. A mech

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