Cover Picture: Hydrocarbon Uptake in the Alkylated Micropores of a Columnar Supramolecular Solid (Angew. Chem. Int. Ed. 42/2006)
✍ Scribed by Thomas J. Taylor; Vladimir I. Bakhmutov; François P. Gabbaï
- Publisher
- John Wiley and Sons
- Year
- 2006
- Tongue
- English
- Weight
- 132 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0044-8249
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Microporous self-assembled materials are attracting a great deal of interest for the storage of gases. The selective uptake and retention of small gaseous molecules, such as dihydrogen, are particularly attractive goals, which may lead to novel storage strategies. [1] In principle, similar strategie
**The mode of the self‐assembly** of **(3,4,5)**^**2**^**G2‐CO**~**2**~**Me** monodendrons changes from a spherical to a pyramidal supramolecular dendrimer upon replacement of the aliphatic chains by partially fluorinated chains. This metamorphosis was verified with a combination of small‐ and wide‐