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Cover Picture: Excited-State Relaxation of Protonated Adenine (ChemPhysChem 5/2007)

✍ Scribed by Dirk Nolting; Rainer Weinkauf; Ingolf V. Hertel; Thomas Schultz


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
28 KB
Volume
8
Category
Article
ISSN
1439-4235

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Excited-State Relaxation of Protonated A
✍ Dirk Nolting; Rainer Weinkauf; Ingolf V. Hertel; Thomas Schultz 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 190 KB

## Abstract The excited state dynamics of protonated adenine in the gas phase were investigated by femtosecond pump–probe transient mass spectroscopy. Adenine was protonated in an electrospray ionization source and transferred to a Paul trap. Two femtosecond laser pulses at 266 nm and 800 nm excite

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## Abstract **The cover picture shows**…︁‥the solvent effect of water upon the lowest‐lying singlet excitation in acetone. The transition, which involves the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbital (LUMO), is blue‐shifted in water (sol) with respect to