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Cover Picture: Dramatic Enhancement of Enone Epoxidation Rates in Nonionic Microemulsions (Chem. Eur. J. 29/2006)

✍ Scribed by Thomas Wielpütz; Thomas Sottmann; Reinhard Strey; Friederike Schmidt; Albrecht Berkessel


Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
378 KB
Volume
12
Category
Article
ISSN
0947-6539

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✦ Synopsis


Microemulsions are used by A. Berkessel et al. on pp. 7565 ff. in epoxidation reactions to investigate how these would accelerate the reactions. The model epoxidation reactions involved α,β‐unsaturated enones and alkaline hydrogen peroxide in different nonionic microemulsions, both in the presence and absence of a phase‐transfer agent (PTA).


📜 SIMILAR VOLUMES


Dramatic Enhancement of Enone Epoxidatio
✍ Thomas Wielpütz; Thomas Sottmann; Reinhard Strey; Friederike Schmidt; Albrecht B 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 181 KB

## Abstract The ability of microemulsions to dissolve polar and non‐polar components with a huge internal interface can overcome the reagent incompatibilities frequently encountered in organic reactions. We investigated model epoxidation reactions of α,β‐unsaturated enones and alkaline hydrogen per