𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Cover Picture: A Phthalocyanine Clathrate of Cubic Symmetry Containing Interconnected Solvent-Filled Voids of Nanometer Dimensions (Angew. Chem. Int. Ed. 46/2005)

✍ Scribed by Neil B. McKeown; Saad Makhseed; Kadhum J. Msayib; Li-Ling Ooi; Madeleine Helliwell; John E. Warren

Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
126 KB
Volume
44
Category
Article
ISSN
0044-8249

No coin nor oath required. For personal study only.

✦ Synopsis

A clathrate formed from a zinc phthalocyanine has an unusual crystal structure with exceptionally large solvent‐filled voids (>8 nm^3^). The “fold‐up cube” in the cover picture shows how six phthalocyanine molecules assemble to form each nanovoid. Solvent molecules, including water, can be exchanged between the voids, while the metal centers embedded in each face offer the potential for catalysis. For more details, see the Communication by N. B. McKeown and co‐workers on page 7546 ff.

📜 SIMILAR VOLUMES

Titelbild: A Phthalocyanine Clathrate of
Titelbild: A Phthalocyanine Clathrate of Cubic Symmetry Containing Interconnected Solvent-Filled Voids of Nanometer Dimensions (Angew. Chem. 46/2005)
✍ Neil B. McKeown; Saad Makhseed; Kadhum J. Msayib; Li-Ling Ooi; Madeleine Helliwe 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 126 KB

**Ein Clathrat** aus einem Zinkphthalocyanin hat eine ungewöhnliche Kristallstruktur mit großen solvensgefüllten Hohlräumen (>8 nm^3^). Der aufgefaltete Würfel auf dem Titelbild zeigt, wie sechs Phthalocyaninmoleküle einen Nanohohlraum aufbauen. Solvensmoleküle, auch Wasser, werden zwischen den Hohl