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Covalently linked [60,70] fullerenes–nitroxide unit for synthesis and characterization

✍ Scribed by Zhiqiang Shi; Yuliang Li; Juhua Xu; Zhongxin Ge; Daoben Zhu


Book ID
108357823
Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
170 KB
Volume
61
Category
Article
ISSN
0022-3697

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Cm or C70 reacts with 2-aminoisobutyric acid and cyclohexanone in chlorobenzene at refluxing through 1,3-dipolar cycloaddition to give [6O]fulleropyrrolidine 1 or [70]fulleropyrrolidine 3 which can be oxidized with MCPBA at room temperature to yield stable nitroxides 2 or 4. The compounds 1 and 3 we