The suggestion has been made' that the most stahle form of protonated phosphinamides has the proton on nitrogen rather than on the phosphoryl oxygen. Among other evidence, the coupling constant, J PNCH, was observed to decrease upon protonation of two different phosphinamides, lb -\_
Coupling vs. conductance for the Jerrum–Sinclair chain
✍ Scribed by V.S. Anil Kumar; H. Ramesh
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 149 KB
- Volume
- 18
- Category
- Article
- ISSN
- 1042-9832
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✦ Synopsis
We address the following question: is the causal coupling method as strong as the conductance method in showing rapid mixing of Markov chains? A causal coupling is a coupling which uses only past and present information, but not information about the future. We answer the above question in the negative by showing that there exists a bipartite graph G such that any causal coupling argument on the Jerrum-Sinclair Markov chain for sampling almost uniformly from the set of perfect and near perfect matchings of G must necessarily take time exponential in the number of vertices in G. In contrast, the above Markov chain on G has been shown to mix in polynomial time using conductance arguments.
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