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Coupling Reactions of the 2-Nitro-2-propyl Anion 1

โœ Scribed by Russell, Glen A.; Danen, Wayne C.


Book ID
126295048
Publisher
American Chemical Society
Year
1966
Tongue
English
Weight
396 KB
Volume
88
Category
Article
ISSN
0002-7863

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Attempts to homocouple 1,3-bis(2-hydroxyhexafluoro-2-propyl)-5iodobenzene (diol iodide) with copper fail to give the desired biphenyl tetrol. However, the dimethyl ether derivative of the diol iodide reacts smoothly with copper to give the biphenyl tetramethyl ether in good yields. The diacetate der