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Coupling of Epoxides to PtII-Complexes with Carbon Dioxide and the Structure of a Cyclic Metallacarbonate

✍ Scribed by Khin-Than Aye; Dr. George Ferguson; Dr. Alan J. Lough; Dr. Richard J. Puddephatt

Publisher: John Wiley and Sons
Year: 1989
Tongue: English
Weight: 239 KB
Volume: 28
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.198907671

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✦ Synopsis

Control experiments confirm the higher reactivity of 1 compared to the bis(phenylsu1fonyl)ethylenes. The reason may be attributed to the relief of strain at the dienophilic carbons upon change of hybridization from spz to sp3. 1.4-Benzodithiin S,S,S,S-tetraoxide, which is structurally related to I , has also been reported to be more reactive: E. Wenkert. C. A. Broka, Finn.

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