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Coupling of Benzynezirconocene with 1,4-Diphenyl-1,3-butadiyne

✍ Scribed by Bredeau, Stéphane; Delmas, Geneviève; Pirio, Nadine; Richard, Philippe; Donnadieu, Bruno; Meunier, Philippe


Book ID
126835745
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
123 KB
Volume
19
Category
Article
ISSN
0276-7333

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Irradiation of 1,4-diphenyl-1,bbutadiyne (DPB) with dimethyl fumarate (DMFu) in deaerated tetrahydrofuran yields a primary 1: 1 photoadduct I and further irradiation of the solution results in the formation of novel 1:2 photoadducts, II and Ill as the secondary photoadducts. The photochemistry of co