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Coupled proton-electron transfer to dithiolene complexes relevant to the molybdenum cofactor of the oxomolybdoenzymes.

✍ Scribed by E.M. Armstrong; M.S. Austerberry; J.H. Birks; C.D. Garner; M. Helliwell; J.A. Joule; J. Russell


Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
50 KB
Volume
43
Category
Article
ISSN
0162-0134

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## Abstract Combined CEPT (coupled electron–proton transfer)/OAT (oxygen atom transfer) reactions were accomplished in (Bu~4~N)~2~[Mo^IV^O(bdtCl~2~)~2~] (1) and (Bu~4~N)~2~[Mo^VI^O~2~(bdtCl~2~)~2~] (2) complexes in aqueous media. The reaction mechanism of the CEPT reaction was analyzed electrochemi