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Coupled magnetic interactions and the Ising-like model for spin crossover in binuclear compounds

✍ Scribed by Pavlik, J.; Nicolazzi, W.; Molnár, G.; Boča, R.; Bousseksou, A.


Book ID
120660056
Publisher
Springer
Year
2013
Tongue
English
Weight
746 KB
Volume
86
Category
Article
ISSN
1434-6036

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Shearing-Like Distortion in Binuclear En
✍ Maria Angels Carvajal; Christophe Aronica; Dominique Luneau; Vincent Robert 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 136 KB

## Abstract The direct control of magnetic interactions in Cu^II^ azido‐bridged binuclear complexes is investigated by means of explicitly correlated ab initio calculations. It is shown that in the end‐to‐end series, the shearing‐like asymmetry parameter __δ__ = __d__~long~(Cu–N) – __d__~short~(Cu–