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Counting the number of active centers in MgCl2-supported Ziegler–Natta catalysts by quenching with 2-thiophenecarbonyl chloride and study on the initial kinetics of propylene polymerization

✍ Scribed by Xianrong Shen; Jie Hu; Zhisheng Fu; Junqin Lou; Zhiqiang Fan


Book ID
118427413
Publisher
Elsevier Science
Year
2013
Tongue
English
Weight
365 KB
Volume
30
Category
Article
ISSN
1566-7367

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Propylene polymerization was investigated with the TiC14/MgCI 4 supported catalyst with the stereoregulating donor pair dibutylphtalate (DBPH)/triethoxyphenylsilane (TEPS) in heptane with A1Et 3 as cocatalyst in the presence of hydrogen. It was shown that there is an activation effect by the influen