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Counterions and Water in Polyelectrolyte Multilayers: A Tale of Two Polycations

โœ Scribed by Jaber, Jad A.; Schlenoff, Joseph B.


Book ID
126790933
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
78 KB
Volume
23
Category
Article
ISSN
0743-7463

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## Abstract The conformational characteristics of polyelectrolytes endโ€grafted on two apposing walls are studied. The monovalent and multivalent counterions are explicitly treated. It is found that the polyelectrolyte brushes undergo a collapse transition in the presence of multivalent counterions