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Counterion-specific swelling behaviour of crosslinked poly(l-glutamic acid) membranes in aqueous alcohols

โœ Scribed by Yang-Il Huh; Nariyoshi Kotake; Mitsuru Satoh; Jiro Komiyama


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
836 KB
Volume
81
Category
Article
ISSN
0376-7388

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The coil-helix transitions of poly (L-glutamic acid) in aqueous alcohol solutions have been investigated for mixed counterion systems. It has been found that coexistence of two kinds of counterion species, i.e., two alkali metal counterions, alkali and alkaline earth metal, and two alkaline earth me

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## Abstract Charged polypeptides containing sulfonate groups were prepared by transesterification of poly(ฮณโ€methyl Lโ€glutamate) with isethionic acid. The coilโ€“helix transition of the sulfonated polypeptides was investigated in aqueous alcohols. Marked counterโ€ion specificity was observed for helix