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Counterion Effects in the Nucleophilic Substitution Reaction of the Acetate Ion with Alkyl Bromides in the Synthesis of Esters

✍ Scribed by Valentín, Elizabeth M.; Montes, Ingrid; Adam, Waldemar

Book ID
120511902
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
498 KB
Volume
86
Category
Article
ISSN
0021-9584

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✍ Kallol K. Ghosh; Jyoti Vaidya; Manmohan Lal Satnami 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 118 KB

## Abstract Pseudo‐first‐order rate constants have been determined for the nucleophilic substitution reactions of __p__‐nitrophenyl acetate with __p__‐chlorophenoxide (4‐ClC~6~H~4~O^−^) and __N__‐phenylbenzohydroxamate (C~6~H~5~CON(C~6~H~5~)O^−^) ions in phosphate buffer (pH 7.7) at 27°C. The effec