Corrole synthesis by dipyrromethane–dicarbinol and 2,2′-bipyrrole condensation

✍ Scribed by Richard A Decréau; James P Collman

• Book ID: 104253422
• Publisher: Elsevier Science
• Year: 2003
• Tongue: French
• Weight: 96 KB
• Volume: 44
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(03)00617-8

✦ Synopsis

A 3 and trans-A 2 B tris-aryl corroles 1a-c have been synthesized in up to 12% yield by BF 3 •Et 2 O-catalyzed condensation of dipyrromethane-dicarbinol and 2,2%-bipyrrole (1:1 ratio) in acetonitrile at room temperature for 24 h.