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Corrigendum to “Reversible heterolytic C–H cleavage by intramolecular C–H activation at diazabutadiene ligands at iridium” [J. Mol. Catal. A 189 (2002) 23–32]

✍ Scribed by Bror Johan Wik; Christian Rømming; Mats Tilset

Book ID: 108211342
Publisher: Elsevier Science
Year: 2004
Tongue: English
Weight: 29 KB
Volume: 219
Category: Article
ISSN: 1381-1169
DOI: 10.1016/j.molcata.2004.05.007

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Reversible heterolytic CH cleavage by i

Reversible heterolytic CH cleavage by intramolecular CH activation at diazabutadiene ligands at iridium

✍ Bror Johan Wik; Christian Rømming; Mats Tilset 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 136 KB

instead give products Cp \* IrClCH 2 C(=NHAr)CMe=N(Ar) + Cl -in which the dab ligand has undergone C-H activation at one of methyl groups of the dab bridge. The C-H cleavage reaction is reversible in the sense that thermally, the cyclometalated Ir complex decomposes to regenerate the free ligand.