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Corrigendum: Preparation of Organoaluminum Reagents from Propargylic Bromides and Aluminum Activated by PbCl2 and Their Regio- and Diastereoselective Addition to Carbonyl Derivatives

✍ Scribed by Li-Na Guo; Hongjun Gao; Peter Mayer; Paul Knochel

Publisher: John Wiley and Sons
Year: 2011
Tongue: English
Weight: 67 KB
Volume: 17
Category: Article
ISSN: 0947-6539
DOI: 10.1002/chem.201190232

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Preparation of Organoaluminum Reagents from Propargylic Bromides and Aluminum Activated by PbCl2 and Their Regio- and Diastereoselective Addition to Carbonyl Derivatives

✍ Li-Na Guo; Hongjun Gao; Peter Mayer; Paul Knochel 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 337 KB 👁 1 views

## Abstract Various propargylic and allenic aluminum reagents have been easily prepared by a direct insertion of aluminum into propargylic bromides in the presence of PbCl~2~ (1 mol %). These organoaluminum reagents react with carbonyl compounds to afford the corresponding allenic alcohols or homop

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