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Correlations of the distribution of spin states in spin crossover compounds

✍ Scribed by H. Spiering; T. Kohlhaas; H. Romstedt; A. Hauser; C. Bruns-Yilmaz; J. Kusz; P. Gütlich

Book ID
104111982
Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
248 KB
Volume
190-192
Category
Article
ISSN
0010-8545

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✦ Synopsis

Short range correlations of the distribution of high spin (HS) and low spin (LS) states show up in thermal spin transition curves, decay curves of the light induced metastable HS state (LIESST state), and in structural features during the spin transitions. Correlations are due to short range interactions between the spin crossover molecules. Short range interactions may compete with omnipresent long range interactions and give rise to interesting spin transition phenomena. In this paper, the effect of correlations on the thermal spin transition in the mixed crystal system [Fe x Zn 1 -x (pic) 3 ]Cl 2 •EtOH (pic =picolylamine) is discussed. In

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