A geometrical approach to the phenomenological theory of phase transitions of the second kind at constant pressure P and variable temperature T is proposed. Equilibrium states of a system at zero external field and fixed P and T are described by points in three-dimensional space with coordinates t/,
โฆ LIBER โฆ
Correlations in the thermodynamical theory of phase transitions of the second kind. I
โ Scribed by A.K. Kanyuka; V.S. Glukhov
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 689 KB
- Volume
- 232
- Category
- Article
- ISSN
- 0378-4371
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โฆ Synopsis
The geometrical approach to the thermodynamical theory of phase transitions of the second kind is further developed for the case when the first non-vanishing derivatives of the Gibbs potential w.r.t, the order parameter and w.r.t, the "critical" correlation parameter are of the fourth order. The critical exponents obtained are the same as in the Landau theory except ~2, ~ exponents which define 2-like peculiarity of the specific heat Ce(T) below as well as above the critical temperature.
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