The competition between different anion orderings, which influences the electronic properties, is illustrated with 3 examples of recent X-ray studies of the alloy (TMTSF) 2 (CI04) I\_× (ReO4)x, (TMTSF) 2 ReO 4 under pressure and (TMTSF) 2 PF2O 2.
Correlations, dimensionality and instabilities in organic superconductors
✍ Scribed by D. Jérome; L. Balicas; K. Behnia; W. Kang; P. Wzietek; L. Hubert; C. Bourbonnais
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 450 KB
- Volume
- 206-207
- Category
- Article
- ISSN
- 0921-4526
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✦ Synopsis
We discuss the role of Coulombic repulsion in organic superconductors exhibiting quasi-one-dimensional transport properties. A recent investigation in high magnetic fields shows that the charge localization occurring at low temperature in a 1-D half-fillled band is suppressed by the 1-D to 2-D (3-D) cross-over in selenium compounds. However, a localization around 30 K in the non-ordered phase can be reactivated by the application of a high transverse magnetic field. This phenomenon provides an interpretation for the large transverse magnetoresistance observed in quasi-l-D conductors with open Fermi surfaces. The intermediate (strong) coupling limit is valid for the spin degree of freedom whereas the charge is governed by the strength of the Umklapp scattering varying by a large factor from sulfur to selenium compounds and under pressure.
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