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Correlations and Predictions of Carboxylic Acid p K a Values Using Intermolecular Structure and Properties of Hydrogen-Bonded Complexes

✍ Scribed by Tao, Li; Han, Jun; Tao, Fu-Ming


Book ID
127153941
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
113 KB
Volume
112
Category
Article
ISSN
1089-5639

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A novel series of hydrogen-bonded solid 1 : 1 acid-base complexes of 15 N-labeled 2,4,6-trimethylpyridine (collidine) with carboxylic acids and their hydrogen bond deuterated analogs were synthesized and studied by 1 H magic angle spinning (MAS) and 15 N cross-polarization NMR with and without MAS.