Correlation of viscoelastic properties with low-resolution 1H-NMR measurements of crosslinking unsaturated polyesters

✍ Scribed by Karin Hietalahti; Mikael Skrifvars; Andrew Root; Franciska Sundholm

• Publisher: John Wiley and Sons
• Year: 1998
• Tongue: English
• Weight: 197 KB
• Volume: 68
• Category: Article
• ISSN: 0021-8995
• DOI: 10.1002/(sici)1097-4628(19980425)68:4<671::aid-app19>3.0.co;2-u

✦ Synopsis

The curing reaction of four synthezized and five commercial unsaturated polyester resins were characterized by low-resolution pulse 1 H-NMR and rheological measurements. The rheological measurements were done both by steady shearing flow and oscillatory shearing flow measurements. For the synthesized resins, which did not contain any inhibiting, these methods were quite comparable when measuring the gel time. Differences in measured gel times could be seen in the commercial resins. We concluded that the time taken from low-resolution pulse 1 H-NMR measurements was not actually the gel time, but the time at which the resins go from the microgel formation stage to the transition stage.