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Correlation of the reactivity of ketones relative to different nucleophiles

โœ Scribed by Finiels, Annie; Geneste, Patrick


Book ID
126180986
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
238 KB
Volume
44
Category
Article
ISSN
0022-3263

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๐Ÿ“œ SIMILAR VOLUMES


The relative reactivity of cyclic ketone
โœ M.T. Reetz; H. Hugel; K. Dresely ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 356 KB

The relative rates of the addition of CH3TiC13 and CH3Ti(OCHMe213 to various cyclic ketones of different ring size have been determined. In contrast to CH3Li and CH3MgCl, significant rate differences were observed. For CH3TiC13 (at -18OC) the following decreasing order in rate pertains, the numbers