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Correlation of Solvolysis Rates. III. 1 t-Butyl Chloride in a Wide Range of Solvent Mixtures 2

โœ Scribed by Fainberg, Arnold H.; Winstein, S.


Book ID
124067811
Publisher
American Chemical Society
Year
1956
Tongue
English
Weight
960 KB
Volume
78
Category
Article
ISSN
0002-7863

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Kinetics of solvolysis of trans-dichloro
โœ Kamal H. Halawani; Cecil F. Wells ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 545 KB

The kinetics of the solvolysis of the hydrophobic ion, Co(4-t-Bupy)dCl:, have been followed in mixtures of water with co-solvents having a hydrophilic tendency, ethane-1,2-diol and 2-methoxyethanol. The variation of ln(rate constant) with the reciprocal of the dielectric constant is nonlinear for bo