A new correlation has been developed for calculation of second virial coefficients of polar compounds. The new procedure uses superimposition of the square well potential function and a term accounting for the dipoltiipole interaction. Parameters for this new correlation have been determined for 13
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Correlation of second virial coefficient for polar fluids
β Scribed by A. Romero; J. Lielmezs
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 480 KB
- Volume
- 145
- Category
- Article
- ISSN
- 0040-6031
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## Abstract A new correlation of second virial coefficients of both polar and nonpolar systems is presented. It uses the PitzerβCurl correlation for nonpolar compounds, but in a modified form. The second virial coefficient of nonhydrogen bonding compounds (ketones, acetaldehyde, acetonitrile, ether