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Correlation of NO stretching frequencies with coordination modes in metal complexes of C-nitroso compounds

✍ Scribed by M. Cameron; B.G. Gowenlock; G. Vasapollo


Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
219 KB
Volume
378
Category
Article
ISSN
0022-328X

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The I70-NMR signals of four true C-nitroso compounds 1 4 appear at particularly low field (1550-1265 ppm), whereas the dimers (azodioxy type) resonate at ca. 400 pprn and the 'isonitroso compounds' ( = quinoneoximes; 5 and 6 ) at ca. 250 ppm. S-Nitroso compounds ( = thionitrites; 8 and 9) show shift