Correlation of electrochemical and ellipsometric data in relation to the kinetics and mechanism of Cu2O electroformation in alkaline solutions
β Scribed by M. R. Gennero De Chialvo; J. O. Zerbino; S. L. Marchiano; A. J. Arvia
- Book ID
- 105033982
- Publisher
- Springer
- Year
- 1986
- Tongue
- English
- Weight
- 787 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0021-891X
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## Soluble Ag(I) species is formed in the early stages of voharnmetric silver electrooxidation in 0.1 hi NaOH and 0.1 M NaOH + 1 M NaClO, solutions at WC, as demonstrated by the rotating ring-disc technique. This result allows a reasonable interpretation of ellipsometric data obtained for the anod
## Abstract The mechanism of anodic dissolution and hence of corrosion of W in alkaline solutions (NaOH, Na~3~PO~4~) has been investigated by measuring anodic Tafel lines by the galvanostatic technique, and calculating both the Tafel slope b and the effect of pH on anode potential as diagnostic cri