The thermoshrinking properties have been studied for the series of N-alkylacrylamide hydrogels (alkyl Γ
methyl, ethyl, isopropyl, and n-propyl), which were prepared by free-radical copolymerization of the alkylacrylamide, sodium acrylate, and N,N-methylenebis(acrylamide) (BIS) in aqueous solution. The reaction mixtures were prepared using the same nominal compositions in an effort to study the effect of the chemical structure of the alkyl substituent on the gel swelling behavior as a function of temperature. The alkyl group was found to have a pronounced effect on the features of gel swelling. Generally, larger alkyl chains produced dramatic decreases in gel transition temperature. In addition, a change in the nature of the swelling behavior from continuous to discontinuous was noted upon changing the alkyl group from ethyl to the two propyl derivatives. Discontinuous transitions were accompanied by hysteresis. The transition temperatures of the isomeric propyl derivatives were found to differ by 12ΠC, with n-propyl exhibiting the lower value. Additionally, a quantitative correlation was found between the gel transition temperatures and the water/octanol partition coefficients for appropriately chosen small molecule model compounds. The transition temperatures of other gels in the series, including the cyclopropyl derivative and the n-propyl/isopropyl copolymer gels (NIPA/NNPA), also fit this correlation.