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Correlation between the stereochemistry and optical activity of chiral dimolybdenum tetracarboxylates and related compounds

✍ Scribed by A. P. Klyagina; I. F. Golovaneva; G. G. Sadikov


Book ID
112447363
Publisher
Springer
Year
1990
Tongue
English
Weight
243 KB
Volume
39
Category
Article
ISSN
1573-9171

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A series of trans-4,5-disubstituted-y-buty~iactones are found to adopt different conformations by aH NMR spectroscopy, whose optical rotation signs are found to depend on the conformations they assume. An empirical correlation rule is proposed for the prediction of optical activity and stereochemist