Correlation between the length of the hydrogen bridge and the frequency of the stretching vibration of the OH group in systems containing hydrogen bonds
β Scribed by Yu. Ya. Efimov; Yu. I. Naberukhin
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 1972
- Tongue
- English
- Weight
- 652 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0022-4766
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π SIMILAR VOLUMES
these two theories are.riot exclusive, but'ratber &&. One of the most char&&stid features of the hydrogen-bond X-H.. .Y is the high anharmonic/ty of the stretching vibration vX\_H,W,Y of the H atom in this bond [I] . As a consequence of this anharrnonicity the c&responding infrared spectrum of the v
A theory is developed to describe a broad IR absorption which appears in the range of a high-frequency stretching vibration of the X-H group involved in the hydrogen bond in solids. The theory is based on the anharmonic coupling mechanism between the high-frequency hydrogen stretching vibration, v(X