The empirical form for the dependence, Tg(n) = Tg(co) (1 + a / n ) , of the glass transition temperature Tg on the average number n of repeat units between crosslinks, is generalized for randomly crosslinked high polymers. The new form, TJn) is based on a correlation study of data for 77 samples of
โฆ LIBER โฆ
Correlation Between the Glass Transition Temperatures and Repeating Unit Structure for High Molecular Weight Polymers.
โ Scribed by Chenzhong Chao; Yuanbin Lin
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 56 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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A new quantitative model is proposed to correlate glass transition temperatures with bond radii-based structural parameters for poly( p-alkyl styrenes), polyolefins, poly(alkyl methacrylates), and poly(alkyl acrylates). The model provides a consistent prediction of the glass transition temperatures