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Correlation between the basicity of carbanions and their ability to transfer an electron

โœ Scribed by Bordwell, Frederick G.; Clemens, Anthony H.


Book ID
126273372
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
415 KB
Volume
46
Category
Article
ISSN
0022-3263

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Correlation between the electronic struc
โœ N. M. Geller; Yu. Ye. Eizner; V. A. Kropachev ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 277 KB ๐Ÿ‘ 2 views

I t is shown that cyclic oxides can be anionically polymerized if the lowest vacant molecular orbital (LVMO) of a C, atom contains a region which can effectively overlap by the electronic cloud of the anionic active centre. This means that LVMO must be a-symmetrical and a t least one of the C, atoms