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Correlation between physical properties of halogenated alkanes and their gas chromatographic behaviour on polar and non-polar stationary phases : II. Brached-chain chloro-, bromo- and iodoalkanes

✍ Scribed by Gianrico Castello; Giuseppina D'Amato


Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
694 KB
Volume
79
Category
Article
ISSN
1873-3778

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✦ Synopsis


Branched-chain chloro-, bromo-and iodoalkanes with four to six carbon atoms have been analyscd by gas chromatography on 3-m glass columns packed with 15 y. of Apiezon L, tricrcsyl phosphate and Carbowax zoM, on DMCS-treated Chromosorb W, using a flame ionization detector.

The retention indices relative to normal iodoalkanes were determined for all compounds, and the retention indices relative to normal chloroalkanes and bromoalkanes were mcaspred and theoretically calculated for branched-chain chloroalkanes and bromoalkanes, r$spectively.