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Correlation between Oscillation Modes and Penetration Rate of Protons in the Three-Phase-Liquid-Membrane Oscillation System

✍ Scribed by Shunkichi Sutou; Hiroshi Yoshihisa; Kazuo Miyamura; Yohichi Gohshi


Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
64 KB
Volume
187
Category
Article
ISSN
0021-9797

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✦ Synopsis


In the three-phase liquid-membrane system consisting of water-nitrobenzene-water, the decrease in pH of aqueous phases is found to be accompanied with the spontaneous electric oscillation of several modes. The increase rates of proton concentration in each aqueous phase are found to differ considerably in each modes of electric oscillation. Furthermore, the presence of an aqueous phase without surfactant is found to accelerate the proton penetration rate through nitrobenzene-water interface. The mechanisms for each mode of oscillation are discussed.