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Correlation between bulk and surface properties in Rb–Pb liquid alloy

✍ Scribed by B.C. Anusionwu; G.A. Adebayo

Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
153 KB
Volume
128
Category
Article
ISSN
0167-7322

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✦ Synopsis

Correlation between bulk thermodynamic properties and surface properties in Rb-Pb liquid alloys has been studied using a statistical model based on compound formation. This study shows that the compound formation in the bulk resulted in an increased surface tension values. A reduced surface concentration of rubidium atoms was also observed. The surface concentration fluctuation at the long wavelength limit S cc s (0) indicates tendency to a regular mixing of alloy components on the surface at high bulk concentrations of Rb.

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The energetics of mixing in Al-Co and Co-Ni liquid alloys has been analysed through the study of surface properties (surface tension and surface composition), dynamic properties (chemical diffusion and viscosity) and microscopic functions (concentration fluctuations in the long-wavelength limit and