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Correlation between basicity and quantum chemical indices of some aliphatic amines

โœ Scribed by A. V. Fokin; N. V. Ioslovich; B. V. Bocharov; V. M. Brusnikina; M. A. Landau; A. A. Lyashenko

Book ID
112443547
Publisher
Springer
Year
1979
Tongue
English
Weight
131 KB
Volume
28
Category
Article
ISSN
1573-9171

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โœ M. Niyaz Khan; Z. Arifin; A. George; I. A. Wahab ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 100 KB ๐Ÿ‘ 1 views

The values of pK a ms (K a ms represents ionization constant of conjugate acid of amine base in mixed waterฯชacetonitrile solvent) for all amines, except for charged amine bases, show a mild decrease (ca. 0.1-0.4 pK units) with the increase in CH 3 CN content from 2 to ฯณ60% v/v. However, the pK a ms