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Correlation between a structural parameter and the carboxyl 13C chemical shielding tensors in compounds containing carboxylic carbon as a functional group

✍ Scribed by N.R. Jagannathan


Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
442 KB
Volume
140
Category
Article
ISSN
0009-2614

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✦ Synopsis


The influence of local molecular geometry on the carboxyl i3C chemical shielding tensom in some organic molecules is investi-Sated. The ur2 component of the tensor shows a linear variation as a function of the OCO bond angle around the carboxyl carbon. The significance of the symmetry factors calculated for these compounds is discussed.