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Correlated interelectronic angle densities of two-electron atoms in position and momentum spaces

✍ Scribed by Toshikatsu Koga; Hisashi Matsuyama

Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
196 KB
Volume
375
Category
Article
ISSN
0009-2614

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✦ Synopsis

Based on multi-configuration Hartree-Fock calculations, correlated interelectronic angle densities are systematically reported for the first 10 members of two-electron atoms in both position and momentum spaces. In position space, the electron correlation is found to modify the uniform Hartree-Fock density so that the density migrates from a small to a large angle, resulting in an average interelectronic angle greater than 90Β°. In momentum space, however, the opposite is true and the two electrons prefer parallel momenta to inverse momenta.

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