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Correction. The Reaction of Primary Amides with Phosgene in the Presence of Hydrogen Chloride

โœ Scribed by Yanigida, Shozo.; Hayama, Hiroshi.; Komori, Saburo.


Book ID
126445501
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
105 KB
Volume
35
Category
Article
ISSN
0022-3263

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The nature of the products from the reaction of TrtPH 2 (1) with an equimolar amount of phosgene strongly depends on the solvent. The initial intermediate 2 was isolated from toluene, but lost CO in dichloromethane, and HCl in diethyl ether, yielding TrtP(H)Cl (3), and (TrtPCO) 2 (4 b), respectively