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Correction. Highly Stereoselective Friedel-Crafts Alkylations via Transannular Reactions

✍ Scribed by Taylor, Stephen; Lilley, Gay; Lilley, Kevin; McCoy, Patricia


Book ID
127196802
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
135 KB
Volume
46
Category
Article
ISSN
0022-3263

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Highly stereoselective Friedel–Crafts al
✍ Bruce P Branchaud; Heather S Blanchette 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 194 KB

Intermolecular additions of highly enantiomerically enriched episulfonium ions onto activated benzene rings are known to accomplish chiral Friedel-Crafts alkylations. Unactivated benzenes are either unreactive or can give low stereoselectivities. Intramolecular cyclizations should be faster than int