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Correct Structure of a Condensation Product C6H12N4O4 from Hydrazine, Formaldehyde and Hydrogen Peroxide

✍ Scribed by Stephen N. Whittleton; Paul Seiler; Jack D. Dunitz

Publisher: John Wiley and Sons
Year: 1981
Tongue: German
Weight: 153 KB
Volume: 64
Category: Article
ISSN: 0018-019X
DOI: 10.1002/hlca.19810640818

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✦ Synopsis

Abstract

The compound mentioned in the title is shown by X‐ray analysis to be 1, 2, 7, 8‐tetraaza‐4, 5, 10, 11‐tetraoxatricyclo [6.4.1.1^2, 7^] tetradecane, contrary to previous suggestions. The torsion angle about the peroxo bonds in the seven‐membered rings in 100°, close to the value in hydrogen peroxide, which would not be possible in a six‐membered ring.

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