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Corrdination-catalyzed skeletal rearrangement of 1,4-dienes

✍ Scribed by Miller, Roy Glenn.


Book ID
120977382
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
396 KB
Volume
89
Category
Article
ISSN
0002-7863

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The Cope rearrangement of 1,5-dienes bearing acyl substituents in the 2-position of the diene system is strongly accelerated by protic and Lewis acids. Table 1. Rearrangement of 2-Acyl-1,5-dienes. Starting Material Acid Mol % Acid Conditionsa Productsb Isolated Yield !A CF3C02H 100 15 min, CH2C12 ,&