Supramolecular assemblies formed by self-associating block copolymers have raised considerable interest in the scientific literature. [1] In most cases, amphiphilic diblock copolymers are dissolved in a solvent selective for one constituent, which results in spherical micelles that consist of a core
Core–Shell–Corona Micelles with a Responsive Shell
✍ Scribed by Jean-François Gohy; Nicolas Willet; Sunil Varshney; Jian-Xin Zhang; Robert Jérôme
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- English
- Weight
- 129 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0044-8249
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## Abstract Reversibly cross‐linked core–shell–corona micelles based on a triblock copolymer composed of poly(aliphatic ester), polyphosphoester, and poly(ethylene glycol) are reported. The triblock copolymer is synthesized through consecutive ring‐opening polymerization of __ε‐__caprolactone and 2