Core-size marker resonance Raman bands of metallotetraphenylporphines
โ Scribed by J. D. Stong; T. G. Spiro; R. J. Kubaska; S. I. Shupack
- Book ID
- 102420901
- Publisher
- John Wiley and Sons
- Year
- 1980
- Tongue
- English
- Weight
- 238 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0377-0486
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๐ SIMILAR VOLUMES
The high frequency resonance Raman skeletal mode frequencies vl, vj, vi,,, v1 1 and y19 of iron complexes of metallooctaethyl porphyrins (MOEP) and metalloprotoporphyrins (MPP) are examined for their dependence on core size and methine bridge stretching force constants. The force constants of these
Soret-excited resonance Raman (RR) spectra are reported for some 40 nonplanar metalloporphyrin complexes. These include (i) copper ฮฒ-octabromo-meso-tetra(para-X-phenyl)porphyrins, Cu [ Br ~8~ T (p- X - P ) P ] ( X = CH ~3~, H , F , CF ~3~, NO ~2~); (ii) copper ฮฒ-octachloro-meso-tetra(para-X-phenyl)p
## Abstract New UV resonance Raman (UVRR) data provide convincing evidence that a characteristic 1511 cm^โ1^ band in the T โ R difference spectra of hemoglobin is due to the overtone of the Trp W18 fundamental at 756 cm^โ1^. Measured isotope shifts for 2โH and 15โN substitution at the indole NH gro