𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Core-Penetrating Rydberg Series of BaF: Single-State and Two-State Fits of New Electronic States in the 4.4 ≤ n* ≤ 14.3 Region

✍ Scribed by Zygmunt J. Jakubek; Robert W. Field

Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
361 KB
Volume
205
Category
Article
ISSN
0022-2852

No coin nor oath required. For personal study only.

✦ Synopsis

We report results of optical-optical double-resonance studies of the Rydberg states of the BaF molecule in the energy region of E = 33 100-38 200 cm(-1) (4.4 </= n* </= 14.3). Barium monofluoride molecules have been produced in a resistively heated high-temperature oven from BaF(2) powder mixed with a small amount of boron powder. We have observed more than 50 new electronic states. Forty-nine of them have been rotationally analyzed and assigned to eight Rydberg series (four (2)Sigma(+), one (2)Pi, two (2)Delta, and one (2)Phi). Single-state and two-state fits have been carried out. Multiple local perturbations have been analyzed. Formation of supercomplexes in the Rydberg spectrum of BaF has been discussed. Copyright 2001 Academic Press.

📜 SIMILAR VOLUMES

Facile Reduction of Early Transition Met
Facile Reduction of Early Transition Metal Halides with Nonconventional, Mild Reductants. Part 5. Gallium and Gallium Dichloride, New Solid-State Reductants in Preparative Transition Metal Chemistry. New, Lower Temperature Syntheses and Convenient Isolation of Hexatantalum Tetradecachloride Octahydrate, Ta6(μ-Cl)12Cl2 (OH2)4×4H2O, and Synthesis and Solid-State Structure of a Tetraalkylammonium Derivative, [N(CH2Ph)Bu3]4 [Ta6(μ-Cl)12Cl6], of the Reduced [Ta6(μ-Cl)12]2+ Cluster Core.
✍ Daniel N. T. Hay; Dale C. Swenson; Louis Messerle 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 40 KB 👁 2 views