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Core-electron spectroscopy of alkaline-earth and transition-metal ions in solution

✍ Scribed by H. Siegbahn; M. Lundholm; S. Holmberg; M. Arbman

Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
353 KB
Volume
110
Category
Article
ISSN
0009-2614

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✦ Synopsis

Coreclccrron

spcctm oftlkdincearth and transition-metal ions in solution have bwn rccordcd. Solvstion cncr~ius for the core-ionized species are derived using thermodynamic cycks whicti involve tlw free-ion to dissolved-ion binding-energy shifts. The distinction between "sofr" and "hard" ion bshaviotu is discussed in relation to 111c sohtion cnsrgics ~cnd multiline features in the traslsition-liictal cure spectra.

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## Abstract The precipitation of barium strontium, calcium, magnesium, zinc, cadmium and lead, manganese, cobalt, nickel and copper 8‐quinolinolates (β€˜oxinates’) was studied from equivalent solutions, at __p__Hs from 4.5 to 10, by optical microscopy: the metal cation and overall β€˜oxinate’ with β€˜oxi