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Copper(II/I) Complexes of a Hexakis(bipyridyl)cyclotriveratrylene Ligand: A Redox-Induced Conformational Switch

โœ Scribed by Wytko, Jennifer A.; Boudon, Corinne; Weiss, Jean; Gross, Maurice


Book ID
127271566
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
305 KB
Volume
35
Category
Article
ISSN
0020-1669

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## Abstract A proposal for a redoxโ€linked conformational gate to proton translocationโ€”a proton pump gateโ€”based upon a transitionโ€metal redoxโ€switchable hemilabile ligand (RHL) system is made. Consideration of the requirements for such a system reveals copper(II) to be the ideal metal centre. To tes