Could Redox-Switched Binding of a Redox-
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Zhicong He; Stephen B. Colbran; Donald C. Craig
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Article
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2003
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John Wiley and Sons
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English
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## Abstract A proposal for a redoxโlinked conformational gate to proton translocationโa proton pump gateโbased upon a transitionโmetal redoxโswitchable hemilabile ligand (RHL) system is made. Consideration of the requirements for such a system reveals copper(II) to be the ideal metal centre. To tes