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Copper(II)−Bis(oxazoline) Catalyzed Asymmetric Diels−Alder Reaction with α′-Arylsulfonyl Enones as Dienophiles

✍ Scribed by Barroso, Santiago; Blay, Gonzalo; Al-Midfa, Lina; Muñoz, M. Carmen; Pedro, José R.


Book ID
120070265
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
210 KB
Volume
73
Category
Article
ISSN
0022-3263

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## Abstract Highly enantioselective Diels–Alder (DA) and inverse‐electron‐demand hetero‐Diels–Alder (HDA) reactions of β,γ‐unsaturated α‐ketoesters with cyclopentadiene catalyzed by chiral __N__,__N′__‐dioxide–Cu(OTf)~2~ (Tf=triflate) complexes have been developed. Quantitative conversion of β,γ‐un